on occasion i get no hot water from this combi boiler. but if i put the heating on for a few minutes the hot water then starts to work. on one occasion you could hear a microswitch flicking on and of and the burners switching on and of. could it be the pressure switch?
try replacing the diapragm washer in the diverter valve. The washer costs a few pound and takes between 1/2 hr and 1hr to replace. Be careful of the springs inside !!!!!!!